Learning new tricks

(by drrubidium) Dec 14 2014

source: Happy Bunny

Just kidding!

My latest learning adventure is coding, which kicked-off Wednesday morning when I completed Hour of Code. Though not completely ignorant to coding (bit of VBA, bit of MATLAB), I'm no expert. Do I need to be an expert? Well, I need to be proficient so that I can do just enough to support my research efforts. I've yet to quantify what just enough is, but I'll know it when I see it. For know, I'm using Codeacademy to pick up new skills and having too much fun doing it! If you follow me on twitter, you've likely seen my coding adventure tweets. I'm tweeting my learning for one simple reason.

I don't know, but I can learn.

Me. With the so-called "terminal degree". Me, an old person. I don't know-it-all. YET. I'm hoping to write a program that will take care of that for me.

 

One response so far

I'm going to the @UNLCollegeofLaw

(by drrubidium) Nov 18 2014

...tomorrow for visit. Recently, I had the opportunity to hear scientist - lawyer Dr. A. Christal Sheppard speak about her interesting career and thought... "Time to visit to my mater's law school!"

I have been interested in legal studies since I was a wee lass spending Saturdays in the public library reading about collateral estoppel.

True story

Plenty of chemists go into law. The American Chemical Society has a whole division called 'Chemistry & The Law'. Now, will I actually go to law school?

There are many, many, many things to consider. Chief among them?

Tuition. WHOA.

Another factor to consider is what type of law to focus on.  CHECK THIS OUT....

 SPACE LAW

I could be a SPACE LAWYER! Picture it!

DrRubidium's legal knowledge is out of this world!

Firefly meets Reno 911!!! Okay, maybe that's not accurate.... I'll find out tomorrow!

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"Nerd alert" gif from giphy

"No idea" gif from Photobucket user dandy_monkey

Money gif from gifbin

UNL Space and Cyber Law image from their twitter account

 

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#GGC14 #DIYscizone Acts of Whimsy! Thank you, donors!

(by drrubidium) Oct 05 2014

When we kicked-off fundraising for year two of the Do-It-Yourself (DIY) Science Zone, we also kicked-off a season of doing wacky things (AKA, 'Acts of Whimsy') to thank donors and celebrate monetary benchmarks.  Below is the collection of all the Acts of Whimsy done by zone volunteers.  Enjoy!

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Top image from here

One response so far

I have to listen to Pink Floyd. You get to pick the album... FOR SCIENCE!

(by drrubidium) Sep 27 2014

UPDATE: RESULTS!!!

PF poll

I'll be listening to 'The Dark Side of the Moon' tomorrow morning while I knock-out some grading.  I might as well do two life-force draining activities at once.  I'll be live-tweeting my listening using the hastag #DSotM.

________________

The moment I've dread has arrived. That's right, the Go Pink Floyd camp has hit the $1000 mark. It's time for me to face the music. The Pink Floyd music.  I've got to listen to an entire album and you'll be able to pick which one by voting in the poll below.  Polls will close October 3rd.

As I'll be listening via Spotify, only studio albums available (or soon to be) on this platform are listed.  I'll live-tweet my listening.  Likely with gifs and an over analysis of lyrics...

11 responses so far

Chemistry of lost gold

(by drrubidium) Sep 17 2014

Funny story... back in 2011, the United Arab Emirates (UAE) seems to have misplaced 50 kg of gold belonging to Crown Financial Solutions.  How much is 50 kg? That's 50 of these shiny bars...

Shiny bars that are worth a lot. [source]

For those adverse to the metric system, 50 kg of gold is about 110.2 lbs. Basically, the UAE just lost a solid gold Kate Moss (which is actually a thing). How much is 50 kg of gold worth?  A cool $2.4 million by 2011 values when gold was $1354.50 per ounce.  Today? The price of gold right now is about $1235.82, so the missing bars are worth about $2.2 million.

50 kg, 110.2 lbs, $2.4 million, $2.2 million... bah! How many atoms of gold are we talking here?!

Elemental gold [source]

If we assume that we've got a total of 50 kg pure gold, this problem is easy peasy! All we need is Au's molecular weight from the periodic table and Avogadro's number.

Picture1

The UAE misplaced 150,000,000,000,000,000,000,000,000 atoms of gold. Fear not! There's something like 10^78 - 10^82 atoms in the observable universe, so 10^26 is a drop in the bucket. A very expensive drop...

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Chemistry is everywhere. Even divorce.

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*Damn sigfigs mean this answer should be rounded by a lot.

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In which I do acts of whimsy... FOR SCIENCE!

(by drrubidium) Aug 25 2014

The DIY Science Zone is back for GeekGirlCon 2014! You know what that means!

  • There will be an fun place at GGC '14 for attendees to get their hands dirty with science!
  • This zone will be staffed by a crew of talented scientists and science educators!
  • We need to raise $6000 and will do acts of whimsy to show our gratitude! As of 9 September 2014, $3393.50 has been raised.

What acts of whimsy will I be doing? To celebrate the first $100, I wore a tiara at work. Since we crossed the $500 mark, I'll be running the CASA Donut Dash on September 14th in this Wonder Woman ensemble.

...but that's not all! Last year, I subjected myself to Nickelback to raise money for the DIY Science Zone.  This year, it's Pink Floyd.

Me too, bro

That's right, I don't like Pink Floyd.  But! I will listen to Pink Floyd - FOR SCIENCE!  For every $1000 the pro-Pink Floyd ("Go PF") camp raises, I'll listen to an entire band album.  I can be saved from listening to Pink Floyd, if the anti-Pink Floyd ("No PF") camp offers up counter donations.  It's Go PF vs. No PF!  Here's how you can make be listen to Pink Floyd or save me from it:

Go PF or No PF, the winner will be science!  No donation is too small and every dollar helps!  Thanks to all our wonderful donors. Yes, even the Go PF ones...

UPDATE!  Go PF camp has raised $595 to get me to listen to Pink Floyd.  The NO PF camp? $275.  Gotta say, last year, Nickelback fans were all about throwing money at the zone. Pink Floyd fans? Um...

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gif from Buzzfeed

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I went to SPACE!!!

(by drrubidium) Aug 04 2014

Pre-launch....

 

rocket science green screen

 

Post-launch... okay, okay... post CGI

 

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Off to #dragoncon I go!

(by drrubidium) Jul 23 2014

DragonCon science

This is the year of multi-genre con madness! First, Emerald City Comicon, then CONvergence, now Dragon Con, and soon GeekGirlCon!  Why multi-genre cons? Because they've got big audiences of hardcore fans that are passionate about every aspect of the genre they love. That's prime science outreach territory!  Breaking Bad fans want to know about meth synthesis methods. Song of Ice and Fire Fans want to know about poisons. Zombie fans want to know how to survive.  Oh, and I'm a HUGE fan. Of zombies, Star Trek, Star Wars, BSG, GoT, Locke & Key, Firefly, all the camp that is the SyFy Original Movie, and much, much more!

Dragon Con's Science Track, led by the fabulous Stephen Granade, has great programming on deck for this year's con!  Check-out the full schedule here.  I'll be participating in the following...


Fri 2030: Zombies and Vampires and Mummies — Oh My! | Location: 202 - Hilton
The undead fascinate us, but what does “undead” mean? Are all undead monsters created equal? Panel scientists will examine life, death, and undeath.
Raychelle Burks, Lali DeRosier, Emily Finke, and Kristopher Hite

Sat 2200The (Non) Science of SyFy Movies | LocationGrand Ballroom West - Hilton
SyFy movies contains some…unique ideas about science. Our scientists discuss the real science, with special guest star SHARKNADO.
David Shiffman, Rachel Pendergrass, Raychelle Burks, Lali DeRosier, and Lisa Hoopes
(Note that this will run in a ballroom while other panels continue in the track room)

Sun 1000The Hands-On Science Power Hour! | LocationAtlanta - Sheraton
Give us an hour and we’ll give you a science buffet! We’ve got twelve hands-on experiments for you to try. How many can you do in an hour?
(Note that this will run in a ballroom while other panels continue in the track room)

Sun 1300Ask a Scientist! Location: Atlanta - Sheraton
You’ve got science questions? We’ve got science answers! Ask our panel of expert scientists anything you want to know about science.
Mika McKinnon, John Cmar, Pamela Gay, Raychelle Burks, David Shiffman, Stephen Granade (moderator)

Sun 2200: The Solve for X Science ShowLocation: Grand Ballroom East - Hilton
Puppet show, PowerPoint karaoke, quiz game, storytelling: the scientists are loose, and nobody knows what could happen next.  Find out more here

 

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Top image created using clip art in PowerPoint

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Grading is coming

(by drrubidium) Jul 14 2014

That's right. Next month.

THE HELL YOU SAY!

A lot of institutions start the fall term in August. That's next month.

For many of us, that means a return of a life-force diminishing activity. Yes, I mean 'grading'.

Since everything is made better with a soundtrack*, I'm sharing my ever-expanding Grading Soundtrack below.  Feel free to drop a relevant^ track in the comments.

  1. The Isley Brothers – Work To Do
  2. Peggy Lee – Why Dont You Do Right
  3. Donna Summer – She Works Hard For The Money
  4. Vince Guaraldi Trio – Linus & Lucy
  5. Queen – Another One Bites The Dust
  6. The Rolling Stones – You Can't Always Get What You Want
  7. John Lee Hooker – One Bourbon, One Scotch, One Beer
  8. Billy Preston – Nothing From Nothing
  9. OK Go – This Too Shall Pass - Marching Band Version
  10. Pet Shop Boys – What Have I Done To Deserve This? - 2001 - Remaster
  11. Jackson 5 – ABC
  12. Johnny Mathis – Too Much, Too Little, Too Late
  13. The Temptations – Ain't Too Proud To Beg
  14. Carole King – It's Too Late
  15. Ray LaMontagne – Trouble
  16. The Main Ingredient – Everybody Plays The Fool
  17. The Friends Of Distinction – Going In Circles
  18. The Spinners – It's A Shame
  19. Lou Rawls – Your Good Thing (Is About To End) - 2006 Digital Remaster
  20. B.B. King – The Thrill Is Gone
  21. Pat Benatar – Heartbreaker
  22. Kool Moe Dee – How Ya Like Me Now - Longer Version
  23. RUN-DMC – It's Tricky
  24. Frank Sinatra – That's Life
  25. Rick James – Cold Blooded
  26. Cake – I Will Survive
  27. Dean Martin – Ain't That A Kick In The Head - 1997 - Remastered
  28. Jamie Foxx – Blame It
  29. Calvin Harris – Sweet Nothing
  30. Nicky Romero – WTF!? (Original Mix)
  31. Club Nouveau – Why You Treat Me So Bad
  32. Ice Cube – Check Yo Self - Remix;
  33. Warren G – Regulate
  34. Solomon Burke – Cry To Me - Single/LP Version
  35. Tyrone Davis – Can I Change My Mind
  36. Daryl Hall & John Oates – I Can't Go For That (No Can Do) - Remastered 2003
  37. Stevie Wonder – All I Do
  38. Bobby Womack – I Can Understand It
  39. Eddie Taylor – I Feel So Bad
  40. The Marvelettes – I Know Better - Stereo Version
  41. Yeah Yeah Yeahs – Heads Will Roll
  42. Mariah Carey – You Don't Know What To Do

________________

*This is a totes false assertion, but it feels true.  Which, by the way, is how Fox News operates.

^Nickelback, Rush, and Pink Floyd are NOT relevant.

________________

Tom Hiddleston gif from here

Kristen Wiig gif from here

2 responses so far

Because she didn't die

(by drrubidium) Jul 08 2014

This post is the second in my Case Book series on old or odd crimes, which began with The suspicious case of Miss Sapwell. The events described herein occured a few years ago in China (Yan et al., 2012).
 

 

  Tiny metallic objects, opaque to x-ray, were spread bilaterally across her chest. A shotgun blast? The metallic objects resembled birdshot, but there was too many of them. There was also no external trauma - no lacerations and no blood.  She had not been shot, yet there they were, a collection of tiny metallic rounds. Whatever they were, and however they got there, these objects were making her terribly ill.

She had come to the hospital complaining of a persistent cough, chest pain, shortness of breath, and fatigue.  Looking at her chest x-ray, a radiologist knew what was causing her respiratory symptoms - those metallic objects in her lungs.  What were they? How did they get there?  The radiologist was baffled.  The patient was hospitalized, but released on the say-so of another doctor.  The only care instruction she was given was bed rest.  Two months later, she was back in the hospital and she was worse.

In addition to her previous symptoms, which had advanced, there were new ailments to be treated.  Abdominal pain, weight loss, ulcers in her mouth, and bleeding gums.  No x-rays were taken during this second visit, which would see her hospitalized for 10 days.  She was released by the same doctor as last time.  Three months later, that very same doctor found her dead in bed.  That doctor was her husband.

Her husband was not a suspect upon her death.  Chiefly because no one thought a crime had been committed. Her long illness, worsening month-by-month, was well documented - along with the attempts to treat whatever it was that ailed her.  Her decline, while perhaps bit mysterious, was not considered suspicious.  The death was ruled "natural", no autopsy was performed, and she was buried the day after she died.

She would not stay buried. Infidelity would cast her death in a new and unnatural light. Her doctor husband - the one that had discharged his sick wife (twice) and found her dead - was caught having an affair with a nurse in his hospital. Their affair had been going on for several months and its discovery provoked her family to request an forensic autopsy*.  While the affair brought suspicion, an autopsy would provide answers. Two months after her death, she was exhumed and examined.

An internal exam cleared-up the mystery of those metallic objects observed in her chest x-ray.  Those metallic objects were mercury globules.

elemental mercury

elemental mercury

Seven months after her first hospital visit and two months after her death, her lungs were full of mercury globules.  These globules weren't just in her lungs, they were also in her pulmonary arteries.  High mercury concentrations were found in her liver, heart, and kidneys.  Her x-ray and presenting systems are nearly textbook for mercury poisoning (mercurialism) of a very particular exposure type. She had been injected with mercury. An injection site wound was found during her autopsy beneath the crease of her left elbow.

Intravenous elemental mercury poisoning is extremely rare. This mode of poisoning is also not a reliable murder weapon.

… no lethal consequences from intravenous injected metal are to be expected…

Elemental mercury, when injected, as opposed to inhaled, caused few of the effects typical of mercurialism (because only a part of mercury is transported into the central nervous system; most of it is deposited in internal organs, lungs, kidneys, aortic valve, as well as at the site of injection), e.g. mercurial tremors and leg pains; however pleuritic chest pain was frequent, whereas renal and central nervous system symptoms were less common. (Lech & Goszcz, 2008, p21)

Mercury made her ill, but something else hastened her demise. Toxicology results showed she had been exposed to cyanide, which is a far more lethal poison than mercury upon injection. Cyanide causes histotoxic hypoxia - cells are unable to use available oxygen and death results.  She was injected with an extraordinarily high dose of cyanide - 1 gram of sodium cyanide dissolved in normal saline. A 100 miligrams of sodium cyanide delivered in the same fashion would have been more than than enough to bring about her quick death. Cyanide, however, wasn't the only injection she received the day of her death.  Shortly before the cyanide, an injection of meperidine (trade name Demerol®) was also administrated.

demoral

Meperidine is a narcotic analgesic used to treat moderate-to-severe pain.  As with the cyanide to follow, meperidine was mixed with a glucose solution prior to injection. With the first two injections - mercury and mepheridine - she was told it was just glucose.  She was told it would make her feel better. She'd a headache a week before her first trip to the hospital.  Her doctor husband told her an injection of glucose would help her headache.  He injected her with 40 milliliters of a glucose solution and 3 milliliters of mercury.  Within a week she was so sick she had to be taken to the hospital, but death did not ensue.  She got worse, and there was the second trip to the hospital, but she didn't die.  He got tired of waiting.  Five months after poisoning her with mercury, he "treated" her again with glucose - merperidine. This drove her to a state of semi-consciousness.  It was then that he injected her with cyanide.

He appears to have obtained the mercury, meperidine, and cyanide at the hospital he worked as a physician. The same hospital he took his ailing wife to. The same hospital the nurse he was having an affair with worked.  Several days before her death, he visited the hospital laboratory and obtained 20 grams of sodium cyanide for ‘‘chemical analysis for his study’’ (Yan et. al., 2012).  Upon being confronted with his wife's autopsy results and evidence of his affair, he confessed all - the timeline, poison dosages, his duplicity.

His lies and his position seem to have provided a sufficient smokescreen for her protracted murder.  Why hadn't the radiologist diagnosed mercury poisoning?  Her doctor husband twice checked her out of the hospital... why didn't that raise an alarm?  Bells didn't ring over his procurement of 20 grams of sodium cyanide using, quite frankly, a thin story - why? Did the hospital not notice the missing mercury and bottle of meperidine?  If his affair hadn't been discovered, he might have gotten away with murder.

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*Her head was not examined at the request of her family (Yan et. al., 2012)

_____________Select References_____________

  • Lech, T.; Goszcz, H. Chronic, long-term presence of mercury due to a single injection of elemental mercury in human, Int J Biochem Biotechnol, 2012, 1, 19-23.
  • Vallant, B.; Deutsch, J.; Muntean, M.; Goessler, W. Intravenous injection of metallic mercury: case report and course of mercury during chelation therapy with DMPS, Clin Tox, 2008, 46, 566–569
  • Yan,P,; Huang, G.; Daoquan, L.; Li, L. Homicide Due to Intravenous Metallic Mercury Injection Followed by Sodium Cyanide Injection, Am J Forensic Med Pathol, 2012, 33, 273-275

_____________Image Attribution_____________

Casebook image from IGAS

Mercury image from Keuka College

Meperidine image from chemspider and Demerol bottle from hospira

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